长江河口水体有机污染物现状分析

对枯水期和丰水期长江河口区5个断面不同深度水样进行检测,共检出有机物200余种,其中定量检出的有机物达53种,有36种属美国EPA控制的有毒有机化合物,列入中国环境优先控制污染物黑名单的有16种.枯水期N-二甲基亚硝胺含量较高,最高值约为1.2 mg·L-1.丰水期2,4-二硝基酚、邻苯二甲酸二丁基苯基酯含量较高,最高值分别约为1.3和1.0 mg·L-1.底层水中有机污染物浓度高于表层和中层.     

长江上游典型区域丰枯转换期水资源变化分析

针对长江上游金沙江下游区域近几年6月和10月出现的较剧烈的水资源丰枯转换现象,以2018年金沙江下游来水过程作为研究案例,考虑金沙江下游流域来水组成及水利工程建设情况,从区间流量分析及上游水库群调蓄影响分析两方面开展了研究工作。研究结果表明:金沙江下游流域丰枯转换主要影响因素为三堆子流量变化,三堆子至溪洛渡区间流量变化影响较小。在6月,上游水库群调蓄对金沙江下游流域丰枯转换影响较大,10月影响相对较小。相关研究成果可为溪洛渡-向家坝梯级水库调度计划制订及实际调度工作提供参考。     

Heavy metals associated with reduced sulfur in sediments from different deposition environments in the Pearl River estuary, China

Distribution of acid volatile sulfur (AVS) and the simultaneously extracted metals (SEM: Cu, Pb, Zn, Cd, Ni) in sediment profiles has been studied at five sites in Pearl River estuary, China. Of the five sampling locations, Nos.1 and 2 are in the middle shoal, Nos.3 and 4 in the west shoal and No. 5 locates to the south of the estuary. The AVS content in the sediments of the middle shoal varies in a small range (0.25–4.06 μmol g⁻¹), while that of west shoal increases with depth from 0 to ultimately 26.09 μmol g⁻¹. The SEM concentration in the sediment profiles at location Nos. 1, 2 and 5 is generally in the range of 0.95±0.2 μmol g⁻¹ with a slight upward increase, while that in the sediment of west shallows are much higher (1.43–2.42 μmol g⁻¹) with a significant upward increase, especially in the upper layer of ca. 15 cm. The observed upward increase of SEM content at all the sites implies that heavy metal contamination of sediment in the Pearl River estuary is increasing. Calculations of the excess heavy metal content which is defined by SEM-AVS molar difference suggests that the upper sediment in the Pearl River estuary, especially on the west shallows, could be a source of heavy metal contaminants and may cause toxicity to the benthos. The site-specific distribution patterns in the AVS and SEM profiles were interpreted according to the hydrogeochemistry of deposition environments.     

River water quality management model using genetic algorithm

Conventional mathematical programming methods, such as linear programming, non linear programming, dynamic programming and integer programming have been used to solve the cost optimization problem for regional wastewater treatment systems. In this study, a river water quality management model was developed through the integration of a genetic algorithm (GA). This model was applied to a river system contaminated by three determined discharge sources to achieve the water quality goals and wastewater treatment cost optimization in the river basin. The genetic algorithm solution, described the treatment plant efficiency, such that the cost of wastewater treatment for the entire river basin is minimized while the water quality constraints in each reach are satisfied. This study showed that genetic algorithm can be applied for river water quality modeling studies as an alternative to the present methods.     

Heavy Metals in the Bed and Suspended Sediments of Anyang River, Korea: Implications for Water Quality

The objective of this study is to compare Anyang River bed sediments with water chemical composition and to assess the anthropogenic chemical inputs into the river system. Eight sampling locations were chosen along the river channel. Bed and suspended river sediments and water samples were collected, and analyzed for their chemical and physical composition. Data revealed that trace element concentrations in the river water were generally below world average, except for As, Mn, Ni and Cr. Among the three phases: water, bed and suspended sediment, more than 99% of the trace elements was associated with the bed sediment. Concentrations of trace elements in the sediment were a function a particle size distribution and organic content. The calculated degrees of enrichment based on the least influenced sample (ASD 1) indicated the river sediments were enriched with respect to background. The enrichment factors for Pb, Zn and As were relatively lower than for Cr, Co, Ni and Zn. The difference in the enrichment seems to reflect the human activities influence in the basin, and specially for Cd. Speciation of the elements in the five different chemical forms in the sediment by sequential extraction indicated that the reducible fraction was predominant for Fe, Zinc and Cu showed an irregular variation among the different fractions; whereas, Cd and Pb were more regular. Zinc and Cu highly existed mostly in exchangeable forms. Acid soluble and reducible forms were also important for most metals. The speciation implies that the metals associated with the sediment are subject to release into water bodies as goechemical variables (pH and Eh) change. Currently, the introduced metals are deposited near the source area and are mostly associated with the sediment, implying that the river bed sediment acts mainly as a sink, rather than a pool. The accumulated and enriched toxic trace elements can pose a potential pollution of river water.     

Portuguese coastal zones and the new coastal management plans

Coastal zones in Portugal, as interface areas between land and sea, have problems related to the growing human pressure in terms of changes in land use associated with urban and industrial occupation, new accessibility (ports, motorways) and traffic flows, intensification of recreational use (beaches, water sports) and excessive fishing. Impacts include deterioration of water quality and sediments; alteration and degradation of natural habitats; new hydrodynamic situations; major landscape changes: and rapid changes in habits and way of life of the local populations and increased exposure of populations and assets to natural and induced risks (storms, accidents, spills, explosions). Plans for the Management of the Coastal Zone (POOC) have been developed and seven of them have been approved, while two similar plans are at a final stage of preparation. Together they cover the entire coast of Portugal. Their implementation and assessment could be a first step towards an integrated management of the Portuguese coastal zones. River Basin Management Plans (PBH) have been concluded and recently approved for the whole country. However, these plans do not consider estuarine systems and some other issues related to coastal systems. The National Water Plan (PNA) is under public presentation and discussion. Several ‘key messages’ are presented in this paper as a contribution for assessment of the proposals of this plan on issues related with coastal waters.     

Stream Invertebrate Communities, Water Quality, and Land-Use Patterns in an Agricultural Drainage Basin of Northeastern Nebraska, USA

We used invertebrate bioassessment, habitat analysis, geographic information system analysis of land use, and water chemistry monitoring to evaluate tributaries of a degraded northeast Nebraska, USA, reservoir. Bimonthly invertebrate collections and monthly water chemistry samples were collected for two years on six stream reaches to identify sources contributing to reservoir degradation and test suitability of standard rapid bioassessment methods in this region. A composite biotic index composed of seven commonly used metrics was effective for distinguishing between differentially impacted sites and responded to a variety of disturbances. Individual metrics varied greatly in precision and ability to discriminate between relatively impacted and unimpacted stream reaches. A modified Hilsenhoff index showed the highest precision (reference site CV = 0.08) but was least effective at discriminating among sites. Percent dominance and the EPT (number of Ephemeroptera, Plecoptera, and Trichoptera taxa) metrics were most effective at discriminating between sites and exhibited intermediate precision. A trend of higher biotic integrity during summer was evident, indicating seasonal corrections should differ from other regions. Poor correlations were evident between water chemistry variables and bioassessment results. However, land-use factors, particularly within 18-m riparian zones, were correlated with bioassessment scores. For example, there was a strong negative correlation between percentage of rangeland in 18-m riparian zones and percentage of dominance in streams (r ² = 0.90, P < 0.01). Results demonstrate that standard rapid bioassessment methods, with some modifications, are effective for use in this agricultural region of the Great Plains and that riparian land use may be the best predictor of stream biotic integrity.     

Locational Probability for a Dammed, Urbanizing Stream: Salt River, Arizona, USA

/ Data from historical aerial photographs analyzed with a GIS show that river channel change on the Salt River in the Phoenix metropolitan area of central Arizona has been driven by large-scale regional flood events and local human activities. Mapping of functional surfaces such as low-flow channels, high-flow channels, islands, bars attached to channel banks, and engineered surfaces shows that during the period from 1935 to 1997, the relative areal coverage of these surfaces has changed. Flood events have caused general changes in sinuosity of the low-flow channel, but islands have remained remarkably consistent in location and size, while channel-side bars have waxed and waned. The most important determinant of local channel form and process is sand and gravel mining, which in some reaches occupies more than 70% of the active channel area. The general location of mining is closely related to the location of the moving urban fringe, which serves as a market for sand and gravel during construction. Quantitative spatial analysis of imagery supplemented by field mapping shows that for each location within the general channel area, it is possible to specify a probability of encountering a low-flow channel or other fluvial features. Maps showing the distribution of these probabilities of occurrence reveal the most probable location and configuration of the channel as it occurred in the past. Some reaches have the low-flow channel located persistently within a limited area as a result of bedrock or sinuosity controls, but other reaches dominated by flow separation or shallow gradient have almost no persistence in channel location from one flood to another.     

长江沿江区域空间结构系统调控研究

长江沿江区域“点－轴－集聚区”空间结构等级系统主要由三级点型式、三级轴型式和三个集聚区组成,形成机制在于其开发条件,中心一边缘疚以及区位和政策因素等,相应的调控措施主要包括：（１）正确处理沿江轴线和三级轴线（省域主要轴线）之间的关系,扩大参与沿江开发开放的地域范围,构筑与沿江轴线相交的新一三级轴线,重点发展一、二级轴线的节点港口城市;（２）加快沿江综合交通运输网建设,特别是沿江铁路建设;（３）优化     

陇南长江流域经济发展和生态重建战略研究

陇南长江流域大多地处嘉陵江上游的源头地区,是一个资源较为富集但经济相对落后、生态环境脆弱且人口压力较大的丘陵山区。本文从可持续发展的角度出发,着眼世纪之交摆脱贫困与奔向小康转换时期经济发展和生态重建的协调演进,提出产业结构调整的基本思路是立足山区优势发展特色农业,市场配置资源、培植支柱工业,商贸、旅游并举、突出第三产业、强化基础设计、增强发展后劲;空间结构重组的战略构想是重点发展东部经８济重心区、